Controlling the Crystalline Structure of Imine-linked 3D Covalent Organic Frameworks
Publication Date
Fall 2-28-2019
Description
We explore the growth mechanism of 3D Covalent Organic Frameworks (COFs) using imine-linked model systems. We confirm that 3D imine COFs crystalize through an amorphous polymer intermediate, whose conditional state is key for preferential generation of the ideal porous structure over the collapsed hydrated form.
Journal
Chemical Communications
Volume
55
First Page
3594
Last Page
3597
Department
Chemistry
Open Access
Link to OA full text
Link to Published Version
https://pubs.rsc.org/en/Content/ArticleLanding/2019/CC/C8CC09571J#!divAbstract
DOI
https://doi.org/10.1039/C8CC09571J
Recommended Citation
Fischbach, Danyon; Rhoades, Grace; Espy, Charlie; Goldberg, Fallon; and Smith, Brian J.. "Controlling the Crystalline Structure of Imine-linked 3D Covalent Organic Frameworks." (2019) : 3594-3597.
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