Title

Molecular Charge-Transfer Cross Sections and Their Correlation with Reactant Ion Structures

Publication Date

1985

Journal

The Journal of Physical Chemistry

Volume

89

Issue

19

First Page

4027

Last Page

4031

Abstract

Charge-transfer cross sections have been obtained by using time-of-flight techniques, and results correlated with reaction energetics and theoretical structures computed by self-consistent field-molecular orbital methods. Ion recombination energies, structures, heats of formation, reaction energy defects, and 3.0-keV charge-transfer cross sections are presented for reactions of molecular and fragment ions produced by electron bombardment ionization of CH30CH, and CH$l molecules. Relationships between experimental cross sections and reaction energetics involving different ion structures are discussed.

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